Hey, if still someone's interested in this bug I know how to semi-fix it. You have to open Privacy and Security options and go to PDF documents pad. Here you have to turn on downloading .pdf files instead of autoopening them in Opera. Thanks to this action pdf doc embedded in the frame on the site gonna turn into URL and you will be able to save this page in .mhtml, just without pdf inside.
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RE: One page can't be saved as mhtml in new Opera since 13.03.2020Opera for Windows